Title

Isomer Distribution of Succinylcyclohexenyl, Acetylcyclohexenyl and Acetylcyclopentenyl Enamines

Authors

A. Gilbert Cook, Valparaiso University
Sarah L. Folk, Valparaiso University

Document Type

Article

Publication Date

6-2008

Abstract

The isomeric distributions of some cyclohexenyl enamines substituted by succinyl or acetyl groups at either the 2- or 6-positions are reported as are the isomeric distributions of similarly substituted cyclopentenyl enamines. Correlation between the C-13 NMR chemical shifts in these enamines and isomer distribution is shown. Density functional molecular modeling is used to demonstrate resonance and electrostatic effects on isomeric distributions.

Recommended Citation

Cook, A. Gilbert and Folk, Sarah L., "Isomer Distribution of Succinylcyclohexenyl, Acetylcyclohexenyl and Acetylcyclopentenyl Enamines" (2008). Chemistry Faculty Publications. 10.
https://scholar.valpo.edu/chem_fac_pub/10